Novel quinoxalinophenanthrophenazine-based molecules as sensors for anions: synthesis and binding investigations

Raad F.S.; El-Ballouli A.O.; Moustafa R.M.; Al-Sayah M.H.; Kaafarani B.R.

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dc.contributor.author	Raad F.S.
dc.contributor.author	El-Ballouli A.O.
dc.contributor.author	Moustafa R.M.
dc.contributor.author	Al-Sayah M.H.
dc.contributor.author	Kaafarani B.R.
dc.contributor.editor
dc.date	2010
dc.date.accessioned	2017-10-03T15:45:21Z
dc.date.available	2017-10-03T15:45:21Z
dc.date.issued	2010
dc.identifier	10.1016/j.tet.2010.02.075
dc.identifier.isbn
dc.identifier.issn	00404020
dc.identifier.uri	http://hdl.handle.net/10938/12601
dc.description.abstract	The design and synthesis of two novel quinoxalinophenanthrophenazine-based anion sensors are reported. Binding studies of these sensors with an array of mono- and polyatomic anions using UV-vis, fluorescence, and NMR titrations have shown 1:1 and 1:2 sensor-to-anion ratios. Binding constants were calculated for anions, which exhibited high affinity for the sensors, including acetate, benzoate, cyanide, and fluoride ions. © 2010 Elsevier Ltd. All rights reserved.
dc.format.extent
dc.format.extent	Pages: (2944-2952)
dc.language	English
dc.publisher	OXFORD
dc.relation.ispartof	Publication Name: Tetrahedron; Publication Year: 2010; Volume: 66; no. 16; Pages: (2944-2952);
dc.relation.ispartofseries
dc.relation.uri
dc.source	Scopus
dc.subject.other
dc.title	Novel quinoxalinophenanthrophenazine-based molecules as sensors for anions: synthesis and binding investigations
dc.type	Article
dc.contributor.affiliation	Raad, F.S., Department of Chemistry, American University of Beirut, Beirut, 1107-2020, Lebanon
dc.contributor.affiliation	El-Ballouli, A.O., Department of Chemistry, American University of Beirut, Beirut, 1107-2020, Lebanon
dc.contributor.affiliation	Moustafa, R.M., Department of Chemistry, American University of Beirut, Beirut, 1107-2020, Lebanon
dc.contributor.affiliation	Al-Sayah, M.H., Department of Biology and Chemistry, American University of Sharjah, Sharjah, United Arab Emirates
dc.contributor.affiliation	Kaafarani, B.R., Department of Chemistry, American University of Beirut, Beirut, 1107-2020, Lebanon
dc.contributor.authorAddress	Al-Sayah, M.H.; Department of Biology and Chemistry, American University of Sharjah, Sharjah, United Arab Emirates; email: malsayah@aus.edu
dc.contributor.authorCorporate	University: American University of Beirut; Faculty: Faculty of Arts and Sciences; Department: Chemistry;
dc.contributor.authorDepartment	Chemistry
dc.contributor.authorDivision
dc.contributor.authorEmail	malsayah@aus.edu; bilal.kaafarani@aub.edu.lb
dc.contributor.faculty	Faculty of Arts and Sciences
dc.contributor.authorInitials	Raad, FS
dc.contributor.authorInitials	El-Ballouli, AO
dc.contributor.authorInitials	Moustafa, RM
dc.contributor.authorInitials	Al-Sayah, MH
dc.contributor.authorInitials	Kaafarani, BR
dc.contributor.authorOrcidID
dc.contributor.authorReprintAddress	Al-Sayah, MH (reprint author), Amer Univ Sharjah, Dept Biol and Chem, Sharjah, U Arab Emirates.
dc.contributor.authorResearcherID
dc.contributor.authorUniversity	American University of Beirut
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dc.description.citedCount	18
dc.description.citedTotWOSCount	18
dc.description.citedWOSCount	18
dc.format.extentCount	9
dc.identifier.articleNo
dc.identifier.coden	TETRA
dc.identifier.pubmedID
dc.identifier.scopusID	77949570572
dc.identifier.url
dc.publisher.address	THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
dc.relation.ispartofConference
dc.relation.ispartofConferenceCode
dc.relation.ispartofConferenceDate
dc.relation.ispartofConferenceHosting
dc.relation.ispartofConferenceLoc
dc.relation.ispartofConferenceSponsor
dc.relation.ispartofConferenceTitle
dc.relation.ispartofFundingAgency
dc.relation.ispartOfISOAbbr	Tetrahedron
dc.relation.ispartOfIssue	16
dc.relation.ispartOfPart
dc.relation.ispartofPubTitle	Tetrahedron
dc.relation.ispartofPubTitleAbbr	Tetrahedron
dc.relation.ispartOfSpecialIssue
dc.relation.ispartOfSuppl
dc.relation.ispartOfVolume	66
dc.source.ID	WOS:000276588400006
dc.type.publication	Journal
dc.subject.otherAuthKeyword	Anion detection
dc.subject.otherAuthKeyword	Chemical sensors
dc.subject.otherAuthKeyword	Fluorescent sensors
dc.subject.otherAuthKeyword	NMR titrations
dc.subject.otherAuthKeyword	Quinoxalinophenanthrophenazine
dc.subject.otherAuthKeyword	Spectroscopic titrations
dc.subject.otherChemCAS	acetic acid, 127-08-2, 127-09-3, 64-19-7, 71-50-1
dc.subject.otherChemCAS	benzoic acid, 532-32-1, 582-25-2, 65-85-0, 766-76-7
dc.subject.otherChemCAS	cyanide, 57-12-5
dc.subject.otherChemCAS	fluoride, 16984-48-8
dc.subject.otherIndex	acetic acid
dc.subject.otherIndex	anion
dc.subject.otherIndex	benzoic acid
dc.subject.otherIndex	cyanide
dc.subject.otherIndex	fluoride
dc.subject.otherIndex	phenazine derivative
dc.subject.otherIndex	quinoxalinophenanthrophenazine
dc.subject.otherIndex	unclassified drug
dc.subject.otherIndex	article
dc.subject.otherIndex	binding affinity
dc.subject.otherIndex	chemical binding
dc.subject.otherIndex	fluorescence
dc.subject.otherIndex	hydrogen bond
dc.subject.otherIndex	nuclear magnetic resonance
dc.subject.otherIndex	priority journal
dc.subject.otherIndex	sensor
dc.subject.otherIndex	synthesis
dc.subject.otherIndex	ultraviolet radiation
dc.subject.otherKeywordPlus	PHOTOINDUCED ELECTRON-TRANSFER
dc.subject.otherKeywordPlus	DIMETHYL-SULFOXIDE SOLUTION
dc.subject.otherKeywordPlus	COLORIMETRIC SENSORS
dc.subject.otherKeywordPlus	FUTURE PERSPECTIVES
dc.subject.otherKeywordPlus	PET SENSORS
dc.subject.otherKeywordPlus	RECEPTORS
dc.subject.otherKeywordPlus	FLUORIDE
dc.subject.otherKeywordPlus	THIOUREA
dc.subject.otherKeywordPlus	RECOGNITION
dc.subject.otherKeywordPlus	EFFICIENT
dc.subject.otherWOS	Chemistry, Organic

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