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Facile preparation of the tosylhydrazone derivatives of a series of racemic trans-3,4-substituted cyclopentanones

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dc.contributor.author Bouhadir K.H.
dc.contributor.author Aleiwe B.A.
dc.contributor.author Fares F.A.
dc.contributor.editor
dc.date 2012
dc.date.accessioned 2017-10-03T15:45:28Z
dc.date.available 2017-10-03T15:45:28Z
dc.date.issued 2012
dc.identifier 10.3390/molecules17010001
dc.identifier.isbn
dc.identifier.issn 14203049
dc.identifier.uri http://hdl.handle.net/10938/12659
dc.description.abstract We report the synthesis and characterization of a variety of trans-3,4-substituted cyclopentanones and the corresponding tosylhydrazone derivatives starting with diethyl fumarate. Protection of the keto group followed by selective monohydrolysis of esters was achieved, resulting in cyclopentanones with different substituents at positions 3 and 4. The tosylhydrazone derivative of each cyclopentanone intermediate was prepared in moderate to good yields. These compounds are potential precursors for functionalized methanofullerenes. © 2012 by the authors.
dc.format.extent
dc.format.extent Pages: (1-14)
dc.language English
dc.publisher BASEL
dc.relation.ispartof Publication Name: Molecules; Publication Year: 2012; Volume: 17; no. 1; Pages: (1-14);
dc.relation.ispartofseries
dc.relation.uri
dc.source Scopus
dc.subject.other
dc.title Facile preparation of the tosylhydrazone derivatives of a series of racemic trans-3,4-substituted cyclopentanones
dc.type Article
dc.contributor.affiliation Bouhadir, K.H., Department of Chemistry, American University of Beirut, Beirut 11-0236, Lebanon
dc.contributor.affiliation Aleiwe, B.A., Department of Chemistry, American University of Beirut, Beirut 11-0236, Lebanon
dc.contributor.affiliation Fares, F.A., Department of Chemistry, American University of Beirut, Beirut 11-0236, Lebanon, Department of Chemistry, Lebanese University, Hadath 6573-14, Lebanon
dc.contributor.authorAddress Bouhadir, K.H.; Department of Chemistry, American University of Beirut, Beirut 11-0236, Lebanon; email: kb05@aub.edu.lb
dc.contributor.authorCorporate University: American University of Beirut; Faculty: Faculty of Arts and Sciences; Department: Chemistry;
dc.contributor.authorDepartment Chemistry
dc.contributor.authorDivision
dc.contributor.authorEmail kb05@aub.edu.lb
dc.contributor.faculty Faculty of Arts and Sciences
dc.contributor.authorInitials Bouhadir, KH
dc.contributor.authorInitials Abou Aleiwe, B
dc.contributor.authorInitials Fares, FA
dc.contributor.authorOrcidID
dc.contributor.authorReprintAddress Bouhadir, KH (reprint author), Amer Univ Beirut, Dept Chem, Beirut 110236, Lebanon.
dc.contributor.authorResearcherID
dc.contributor.authorUniversity American University of Beirut
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dc.description.citedCount 1
dc.description.citedTotWOSCount 1
dc.description.citedWOSCount 1
dc.format.extentCount 14
dc.identifier.articleNo
dc.identifier.coden MOLEF
dc.identifier.pubmedID 22193210
dc.identifier.scopusID 84856168011
dc.identifier.url
dc.publisher.address POSTFACH, CH-4005 BASEL, SWITZERLAND
dc.relation.ispartofConference
dc.relation.ispartofConferenceCode
dc.relation.ispartofConferenceDate
dc.relation.ispartofConferenceHosting
dc.relation.ispartofConferenceLoc
dc.relation.ispartofConferenceSponsor
dc.relation.ispartofConferenceTitle
dc.relation.ispartofFundingAgency
dc.relation.ispartOfISOAbbr Molecules
dc.relation.ispartOfIssue 1
dc.relation.ispartOfPart
dc.relation.ispartofPubTitle Molecules
dc.relation.ispartofPubTitleAbbr Molecules
dc.relation.ispartOfSpecialIssue
dc.relation.ispartOfSuppl
dc.relation.ispartOfVolume 17
dc.source.ID WOS:000299535700001
dc.type.publication Journal
dc.subject.otherAuthKeyword Cyclopentanone
dc.subject.otherAuthKeyword Ethylene ketal
dc.subject.otherAuthKeyword Monohydrolysis
dc.subject.otherAuthKeyword Tosyl hydrazone
dc.subject.otherChemCAS cyclopentanone, 120-92-3
dc.subject.otherChemCAS fumaric acid diethyl ester, 623-91-6
dc.subject.otherChemCAS Cyclopentanes
dc.subject.otherChemCAS Fumarates
dc.subject.otherChemCAS cyclopentanone, 120-92-3
dc.subject.otherChemCAS diethyl fumarate, 623-91-6
dc.subject.otherIndex cyclopentane derivative
dc.subject.otherIndex cyclopentanone
dc.subject.otherIndex fumaric acid derivative
dc.subject.otherIndex fumaric acid diethyl ester
dc.subject.otherIndex article
dc.subject.otherIndex chemistry
dc.subject.otherIndex hydrolysis
dc.subject.otherIndex synthesis
dc.subject.otherIndex Cyclopentanes
dc.subject.otherIndex Fumarates
dc.subject.otherIndex Hydrolysis
dc.subject.otherKeywordPlus FULLERENE DERIVATIVES
dc.subject.otherKeywordPlus C-60
dc.subject.otherKeywordPlus INHIBITION
dc.subject.otherKeywordPlus ACID
dc.subject.otherWOS Chemistry, Organic


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