| dc.contributor.author | Kaafarani B.R. |
| dc.contributor.author | El-Ballouli A.O. |
| dc.contributor.author | Trattnig R. |
| dc.contributor.author | Fonari A. |
| dc.contributor.author | Sax S. |
| dc.contributor.author | Wex B. |
| dc.contributor.author | Risko C. |
| dc.contributor.author | Khnayzer R.S. |
| dc.contributor.author | Barlow S. |
| dc.contributor.author | Patra D. |
| dc.contributor.author | Timofeeva T.V. |
| dc.contributor.author | List E.J.W. |
| dc.contributor.author | Bredas J.-L. |
| dc.contributor.author | Marder S.R. |
| dc.contributor.editor | |
| dc.date | 2013 |
| dc.date.accessioned | 2017-10-03T15:45:32Z |
| dc.date.available | 2017-10-03T15:45:32Z |
| dc.date.issued | 2013 |
| dc.identifier | 10.1039/c2tc00474g |
| dc.identifier.isbn | |
| dc.identifier.issn | 20507534 |
| dc.identifier.uri | http://hdl.handle.net/10938/12702 |
| dc.description.abstract | Tetrahydropyrene and pyrene have been functionalized in their 2,7-positions with carbazole and 3,6-di-tert-butylcarbazole groups, and the properties of these new compounds are compared to analogous carbazole and 3,6-di-tert- butylcarbazole derivatives of benzene and biphenyl using X-ray crystallography, UV-vis absorption and fluorescence spectroscopy, electrochemistry, and quantum-chemical calculations. The absorption spectra are similar to those of their biphenyl-bridged analogues, although TD-DFT calculations indicate a different description of the excited states in the pyrene case, with the lowest observed absorption no longer corresponding to the S0 → S 1 transition. The 3,6-di-tert-butylcarbazole compounds show reversible electrochemical oxidations; the benzene, biphenyl, tetrahydropyrene, or pyrene bridging groups have little impact on the first oxidation potential. Bilayer organic light-emitting diodes incorporating the tetrahydropyrene and pyrene derivatives as emitters show deep-blue electroluminescence. This journal is © The Royal Society of Chemistry 2013. |
| dc.format.extent | |
| dc.format.extent | Pages: (1638-1650) |
| dc.language | English |
| dc.publisher | CAMBRIDGE |
| dc.relation.ispartof | Publication Name: Journal of Materials Chemistry C; Publication Year: 2013; Volume: 1; no. 8; Pages: (1638-1650); |
| dc.relation.ispartofseries | |
| dc.relation.uri | |
| dc.source | Scopus |
| dc.subject.other | |
| dc.title | Bis(carbazolyl) derivatives of pyrene and tetrahydropyrene: Synthesis, structures, optical properties, electrochemistry, and electroluminescence |
| dc.type | Article |
| dc.contributor.affiliation | Kaafarani, B.R., Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon |
| dc.contributor.affiliation | El-Ballouli, A.O., Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon |
| dc.contributor.affiliation | Trattnig, R., NanoTecCenter Weiz Forschungsgesellschaft MbH, Franz-Pichler-Straße 32, A-8160 Weiz, Austria |
| dc.contributor.affiliation | Fonari, A., Department of Biology and Chemistry, New Mexico Highlands University, Las Vegas, NM 87701, United States |
| dc.contributor.affiliation | Sax, S., NanoTecCenter Weiz Forschungsgesellschaft MbH, Franz-Pichler-Straße 32, A-8160 Weiz, Austria |
| dc.contributor.affiliation | Wex, B., Department of Natural Sciences, Lebanese American University, Byblos, Lebanon |
| dc.contributor.affiliation | Risko, C., School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332, United States |
| dc.contributor.affiliation | Khnayzer, R.S., Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon |
| dc.contributor.affiliation | Barlow, S., School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332, United States |
| dc.contributor.affiliation | Patra, D., Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon |
| dc.contributor.affiliation | Timofeeva, T.V., Department of Biology and Chemistry, New Mexico Highlands University, Las Vegas, NM 87701, United States |
| dc.contributor.affiliation | List, E.J.W., NanoTecCenter Weiz Forschungsgesellschaft MbH, Franz-Pichler-Straße 32, A-8160 Weiz, Austria, Institut für Festkörperphysik, Technische Universität, Graz Petersgasse 16, A-8010 Graz, Austria |
| dc.contributor.affiliation | Brédas, J.-L., School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332, United States |
| dc.contributor.affiliation | Marder, S.R., School of Chemistry and Biochemistry, Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332, United States |
| dc.contributor.authorAddress | Kaafarani, B.R.; Department of Chemistry, American University of Beirut, Beirut 1107-2020, Lebanon; email: bilal.kaafarani@aub.edu.lb |
| dc.contributor.authorCorporate | University: American University of Beirut; Faculty: Faculty of Arts and Sciences; Department: Chemistry; |
| dc.contributor.authorDepartment | Chemistry |
| dc.contributor.authorDivision | |
| dc.contributor.authorEmail | bilal.kaafarani@aub.edu.lb |
| dc.contributor.faculty | Faculty of Arts and Sciences |
| dc.contributor.authorInitials | Kaafarani, BR |
| dc.contributor.authorInitials | El-Ballouli, AO |
| dc.contributor.authorInitials | Trattnig, R |
| dc.contributor.authorInitials | Fonari, A |
| dc.contributor.authorInitials | Sax, S |
| dc.contributor.authorInitials | Wex, B |
| dc.contributor.authorInitials | Risko, C |
| dc.contributor.authorInitials | Khnayzer, RS |
| dc.contributor.authorInitials | Barlow, S |
| dc.contributor.authorInitials | Patra, D |
| dc.contributor.authorInitials | Timofeeva, TV |
| dc.contributor.authorInitials | List, EJW |
| dc.contributor.authorInitials | Bredas, JL |
| dc.contributor.authorInitials | Marder, SR |
| dc.contributor.authorOrcidID | |
| dc.contributor.authorReprintAddress | Kaafarani, BR (reprint author), Amer Univ Beirut, Dept Chem, Beirut 11072020, Lebanon. |
| dc.contributor.authorResearcherID | Risko, Chad-A-9785-2014; Bredas, Jean-Luc-A-3431-2008 |
| dc.contributor.authorUniversity | American University of Beirut |
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| dc.description.citedCount | 11 |
| dc.description.citedTotWOSCount | 15 |
| dc.description.citedWOSCount | 15 |
| dc.format.extentCount | 13 |
| dc.identifier.articleNo | |
| dc.identifier.coden | |
| dc.identifier.pubmedID | |
| dc.identifier.scopusID | 84876927079 |
| dc.identifier.url | |
| dc.publisher.address | THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND |
| dc.relation.ispartofConference | |
| dc.relation.ispartofConferenceCode | |
| dc.relation.ispartofConferenceDate | |
| dc.relation.ispartofConferenceHosting | |
| dc.relation.ispartofConferenceLoc | |
| dc.relation.ispartofConferenceSponsor | |
| dc.relation.ispartofConferenceTitle | |
| dc.relation.ispartofFundingAgency | |
| dc.relation.ispartOfISOAbbr | J. Mater. Chem. C |
| dc.relation.ispartOfIssue | 8 |
| dc.relation.ispartOfPart | |
| dc.relation.ispartofPubTitle | Journal of Materials Chemistry C |
| dc.relation.ispartofPubTitleAbbr | J. Mater. Chem. C |
| dc.relation.ispartOfSpecialIssue | |
| dc.relation.ispartOfSuppl | |
| dc.relation.ispartOfVolume | 1 |
| dc.source.ID | WOS:000314807800015 |
| dc.type.publication | Journal |
| dc.subject.otherAuthKeyword | |
| dc.subject.otherChemCAS | |
| dc.subject.otherIndex | Bilayer organic light-emitting diodes |
| dc.subject.otherIndex | Bridging groups |
| dc.subject.otherIndex | Functionalized |
| dc.subject.otherIndex | Oxidation potentials |
| dc.subject.otherIndex | Pyrene derivatives |
| dc.subject.otherIndex | Quantum-chemical calculation |
| dc.subject.otherIndex | Td-dft calculations |
| dc.subject.otherIndex | UV-vis absorptions |
| dc.subject.otherIndex | Benzene |
| dc.subject.otherIndex | Chemical compounds |
| dc.subject.otherIndex | Density functional theory |
| dc.subject.otherIndex | Electrochemical oxidation |
| dc.subject.otherIndex | Electrochemistry |
| dc.subject.otherIndex | Electroluminescence |
| dc.subject.otherIndex | Fluorescence spectroscopy |
| dc.subject.otherIndex | Light emitting diodes |
| dc.subject.otherIndex | Optical properties |
| dc.subject.otherIndex | Quantum chemistry |
| dc.subject.otherIndex | X ray crystallography |
| dc.subject.otherIndex | Pyrene |
| dc.subject.otherKeywordPlus | LIGHT-EMITTING-DIODES |
| dc.subject.otherKeywordPlus | DENSITY-FUNCTIONAL THEORY |
| dc.subject.otherKeywordPlus | POLYCYCLIC AROMATIC-HYDROCARBONS |
| dc.subject.otherKeywordPlus | HOLE-TRANSPORTING MATERIALS |
| dc.subject.otherKeywordPlus | MIXED-VALENCE SYSTEMS |
| dc.subject.otherKeywordPlus | PHOTOPHYSICAL PROPERTIES |
| dc.subject.otherKeywordPlus | EXCITED-STATES |
| dc.subject.otherKeywordPlus | PHOSPHORESCENT OLEDS |
| dc.subject.otherKeywordPlus | AB-INITIO |
| dc.subject.otherKeywordPlus | SPECTROSCOPIC PROPERTIES |
| dc.subject.otherWOS | Materials Science, Multidisciplinary |
| dc.subject.otherWOS | Physics, Applied |
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