Harmonicity and anharmonicity of phonon and surface phonon-polariton in high symmetry directions in wurtzite AlN

Abstract

We report on the potential of self-nucleated AlN single crystals as tunable near-field infrared sources. A self-nucleated AlN crystal was grown with appropriate care to ensure minimal contact with crucible walls or other crystals. The grown crystal exhibits natural AlN growth characteristics with several well-developed facets of different orientations. The characteristics of surface-phonon-polariton (SPhP) modes on the developed crystal facets have been investigated. Reflectivity spectra were recorded from five facets of different orientations. The measured spectra were analyzed by a model taking into account the dependence of harmonicity and anharmonicity of the excited zone center optical phonons on the surface orientation. Consequently, the dielectric properties that determine the condition of existence, dispersion relations, and lifetimes of the SPhP modes were accurately retrieved. The dielectric functions were determined as a function of the angle of incidence and used to compute the characteristics of the SPhP modes on each of the measured facets. We found that facets of different orientations exhibit SPhP modes of different frequencies and lifetimes, which makes the investigated self-nucleated crystal potential candidates for tunable near-field infrared sources. © 2017 Author(s).