Electronic structure study of the mechanism of alkyl radical carbonylation mediated by transition metal complexes - by Nadeen Hassan Nsouli

Nsouli, Nadeen Hassan

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Electronic structure study of the mechanism of alkyl radical carbonylation mediated by transition metal complexes - by Nadeen Hassan Nsouli

Nsouli, Nadeen Hassan

URI: http://hdl.handle.net/10938/6916

Date: 2005

Abstract:

In presence of ketones, [Rh(PMe3)2(CO)Cl] is known to photo-catalyze the industr ially important transformation of alkanes into aldehydes. There is experimental evidence that the mechanism in this system starts with hydrogen atom abstraction from the alka

Description:

Thesis (M.S.)--American University of Beirut, Dept. of Chemistry, 2005.;"Advisor: Dr. Faraj Hasanayn, Assistant Professor, Chemistry--Member of Committee: Dr. Mazen Al-Ghoul, Associate Professor, Chemistry--Member of Committee: Dr. Najat A. Saliba, Assist

Bibliography: leaves 84-93.

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Electronic structure study of the mechanism of alkyl radical carbonylation mediated by transition metal complexes - by Nadeen Hassan Nsouli

Electronic structure study of the mechanism of alkyl radical carbonylation mediated by transition metal complexes - by Nadeen Hassan Nsouli

Abstract:

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